All Notebooks | Help | Support | About
20th August 2013 @ 09:08

This post is compatible for submission to ChemSpider Reactions.

See ChemSpider Reactions template - help and further information for help when using it.

Reaction information

*#Reaction file
overallscheme_34.cdx
*Reaction file type CDX
*Procedure See child reaction steps
*Yield (%)  
*Type of Yield  
Reference(s)
PhD Thesis - 16Sep2010_final p16.pdf
 
PhD Thesis - 16Sep2010_final p124-125.pdf
Further information Compound 34: 1,4-bis(4-(2-(trimethylsilyl)ethylthio)phenyl)buta-1,3-diyne

For multistep reactions (or their steps):

Overall reaction? True
For overall reaction - links to child reaction steps

Reaction 30: Protection of thiol with alkylsilane: (2-(4-bromophenylthio)ethyl)trimethylsilane

Reaction 31: Sonogashira Coupling: (2-(trimethylsilyl)ethyl)(4-(2-(trimethylsilyl)ethynyl)phenyl)sulfane

Reaction 32: Deprotection of (2-(Trimethylsilyl)ethyl)(4-(2-(trimethylsilyl)ethynyl)phenyl)sulfane: (2-(4-ethynylphenylthio)ethyl)trimethylsilane

Reaction 34: Sonogashira Coupling: 1,4-bis(4-(2-(trimethylsilyl)ethylthio)phenyl)buta-1,3-diyne

For step in multistep reaction - link to previous reaction step  
For step in multistep reaction - link to following reaction step  
Attached Files
overallscheme_34.cdx
PhD Thesis - 16Sep2010_final p16.pdf
PhD Thesis - 16Sep2010_final p124-125.pdf