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22nd August 2013 @ 13:44

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Reaction information

*#Reaction file
overallscheme_52.cdx
*Reaction file type CDX
*Procedure See child reaction steps
*Yield (%)  
*Type of Yield  
Reference(s)

PhD Thesis - 16Sep2010_final p26.pdf
 
PhD Thesis - 16Sep2010_final p138.pdf

Cannon, J. G.; Liang, C.-Y. Synth. Comm. 1995, 25, 14, 2079-2089.

Swepston, P. N.; Lin, S.-T.; Hawkins, A.; Humphrey, S.; Siegel, S.; Cordes, A. W. J. Org. Chem. 1981, 46, 3754-3756.

Whistler, R. L.; Campbell, C. S. J. Org. Chem. 1966, 31, 816-818

Further information Compound 52: trans,trans-S,S’-bi(cyclohexane)-4,4’-diylbis(methylene)diethanethioate

For multistep reactions (or their steps):

Overall reaction? True
For overall reaction - links to child reaction steps

Reaction 48: Hydrogenation of methyl ester biphenyl-dicarboxylate: dimethylbi(cyclohexane)-4,4’-dicarboxylate

Reaction 49: Hydrolysis of dimethylbi(cyclohexane)-4,4’-dicarboxylate: trans,trans-bi(cyclohexane)-4,4’-dicarboxylic acid

Reaction 50: Reduction of trans,trans-bi(cyclohexane)-4,4’-dicarboxylic acid: trans,trans-bi(cyclohexane)-4,4’-diyldimethanol

Reaction 51: Bistosylation of trans,trans-bi(cyclohexane)-4,4’-diyldimethanol: trans,trans-bi(cyclohexane)-4,4’-diylbis(methylene)bis(4-methylbenzene-sulfonate)

Reaction 52: Displacement of tosyl-group using a thioacetate: trans,trans-S,S’-bi(cyclohexane)-4,4’-diylbis(methylene)diethanethioate

For step in multistep reaction - link to previous reaction step  
For step in multistep reaction - link to following reaction step  
Attached Files
overallscheme_52.cdx