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23rd August 2013 @ 12:51

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Reaction information

*#Reaction file
overallscheme_4.cdx
*Reaction file type CDX
*Procedure See child reaction steps
*Yield (%)  
*Type of Yield  
Reference(s)
PhD Thesis - 16Sep2010_final p11.pdf
PhD Thesis - 16Sep2010_final p106.pdf
Further information 1-acetylthio-4-iodobenzene

For multistep reactions (or their steps):

Overall reaction? True
For overall reaction - links to child reaction steps

Reaction 1: Nucleophilic substitution of 4-iodophenol to dimethylthiocarbamoyl chloride: O-4-Iodophenyl-N,N-dimethylthiocarbamate

Reaction 2: Rearrangement from O-carbamate to S-carbamate: S-4-Iodothiophenyl-N,N-dimethylcarbamate

Reaction 3: Removal of S-carbamate protecting group: 4-Iodothiophenol

Reaction 4: Substitution of 4-iodothiophenol with acetyl chloride: 1-acetylthio-4-iodobenzene

For step in multistep reaction - link to previous reaction step  
For step in multistep reaction - link to following reaction step

Reaction 12: Bidirectional Sonogashira Coupling: 1,4-didodecyl-2,5-(2-(4-(2-(4-thioacetylphenyl)ethynyl)phenyl)-ethynyl)benzene

Reaction 17: Bidirectional Sonogashira Coupling: 1,4-didodecyl-2,5-bis(2-(4-(2-(4-(2-(4-thioacetylphenyl)ethynyl)phenyl) ethynyl)phenyl)ethynyl)benzene

Attached Files
overallscheme_4.cdx