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23rd August 2013 @ 12:51
This post is compatible for submission to ChemSpider Reactions. See [blog=44639]ChemSpider Reactions template - help and further information[/blog] for help when using it. Reaction information *#Reaction file [data]38270[/data] *Reaction file type CDX *Procedure See child reaction steps *Yield (%)   *Type of Yield   Reference(s) [data]38179[/data][data]38205[/data] Further information 1-acetylthio-4-iodobenzene For multistep reactions (or their steps): Overall reaction? True For overall reaction - links to child reaction steps Reaction 1: Nucleophilic substitution of 4-iodophenol to dimethylthiocarbamoyl chloride: O-4-Iodophenyl-N,N-dimethylthiocarbamate Reaction 2: Rearrangement from O-carbamate to S-carbamate: S-4-Iodothiophenyl-N,N-dimethylcarbamate Reaction 3: Removal of S-carbamate protecting group: 4-Iodothiophenol Reaction 4: Substitution of 4-iodothiophenol with acetyl chloride: 1-acetylthio-4-iodobenzene For step in multistep reaction - link to previous reaction step   For step in multistep reaction - link to following reaction step Reaction 12: Bidirectional Sonogashira Coupling: 1,4-didodecyl-2,5-(2-(4-(2-(4-thioacetylphenyl)ethynyl)phenyl)-ethynyl)benzene Reaction 17: Bidirectional Sonogashira Coupling: 1,4-didodecyl-2,5-bis(2-(4-(2-(4-(2-(4-thioacetylphenyl)ethynyl)phenyl) ethynyl)phenyl)ethynyl)benzene
Attached Files
overallscheme_4.cdx