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28th August 2013 @ 13:36

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Reaction information

*#Reaction file
overallscheme_20.cdx
*Reaction file type CDX
*Procedure See child reaction steps
*Yield (%)  
*Type of Yield  
Reference(s)
PhD Thesis - 16Sep2010_final p14.pdf
PhD Thesis - 16Sep2010_final p116.pdf
Further information Compound 20: 1,4-didodecyl-2,5-bis-(2-(4-cyanobenzil)ethynyl)benzene

For multistep reactions (or their steps):

Overall reaction? True
For overall reaction - links to child reaction steps

Reaction 5: Nickel-catalysed Alkylation of dichlorobenzene with dodecylmagnesium bromide: 1,4-didodecylbenzene

Reaction 6: Halogenation of 1,4-didodecylbenzene with Iodine: 1,4-didodecyl-2,5-diiodobenzene

Reaction 18: Sonogashira Coupling: 4-(2-(Trimethylsilyl)ethynyl)benzonitrile

Reaction 19: Deprotection of 4-(2-(trimethylsilyl)ethynyl)benzonitrile: 4-ethynylbenzonitrile

Reaction 20: Bidirectional Sonogashira Coupling: 1,4-didodecyl-2,5-bis-(2-(4-cyanobenzil)ethynyl)benzene

For step in multistep reaction - link to previous reaction step  
For step in multistep reaction - link to following reaction step  
Attached Files
overallscheme_20.cdx