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29th August 2013 @ 09:14

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Reaction information

*#Reaction file
*Reaction file type CDX
*Procedure See child reaction steps
*Yield (%)  
*Type of Yield  
PhD Thesis - 16Sep2010_final p14.pdf
PhD Thesis - 16Sep2010_final p119-120.pdf
Further information Compound 25: 1,4-didodecyl-2,5-bis(2-(4-(2-(4-methylthio)phenyl)ethynyl)phenyl)-ethynyl-benzene

For multistep reactions (or their steps):

Overall reaction? True
For overall reaction - links to child reaction steps

Reaction 5: Nickel-catalysed Alkylation of dichlorobenzene with dodecylmagnesium bromide: 1,4-didodecylbenzene

Reaction 6: Halogenation of 1,4-didodecylbenzene with Iodine: 1,4-didodecyl-2,5-diiodobenzene

Reaction 21: Sonogashira Coupling: trimethyl(2-(4-(methylthio)phenyl)ethynyl)silane

Reaction 22: Sonogashira Coupling: 2-(4-(2-(4-bromophenyl)ethynyl)phenyl)methylthioether

Reaction 23: Sonogashira Coupling: trimethyl(2-(4-(2-(4-(methylthio)phenyl)ethynyl)phenyl)ethynyl)silane

Reaction 24: Deprotection of TMS group: 2-(4-(2-(4-(methylthio)phenyl)ethynyl)phenyl)ethynylene

Reaction 25: Bidirectional Sonogashira Coupling: 1,4-didodecyl-2,5-bis(2-(4-(2-(4-methylthio)phenyl)ethynyl)phenyl)-ethynyl-benzene

For step in multistep reaction - link to previous reaction step  
For step in multistep reaction - link to following reaction step  
Attached Files