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29th August 2013 @ 11:00

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Reaction information

*#Reaction file
overallscheme_28.cdx
*Reaction file type CDX
*Procedure See child reaction steps
*Yield (%)  
*Type of Yield  
Reference(s)
PhD Thesis - 16Sep2010_final p14.pdf
PhD Thesis - 16Sep2010_final p121.pdf
Further information Compound 28: 1,4-bis(2-(4-(2-(4-methylthio)phenyl)ethynyl)phenyl)ethynyl-2,5-bis(octyl-oxy)-benzene

For multistep reactions (or their steps):

Overall reaction? True
For overall reaction - links to child reaction steps

Reaction 21: Sonogashira Coupling: trimethyl(2-(4-(methylthio)phenyl)ethynyl)silane

Reaction 22: Sonogashira Coupling: 2-(4-(2-(4-bromophenyl)ethynyl)phenyl)methylthioether

Reaction 23: Sonogashira Coupling: trimethyl(2-(4-(2-(4-(methylthio)phenyl)ethynyl)phenyl)ethynyl)silane

Reaction 24: Deprotection of TMS group: 2-(4-(2-(4-(methylthio)phenyl)ethynyl)phenyl)ethynylene

Reaction 26: Nucleophilic substitition of hydroquinone to octylbromide: 1,4-bis(octyloxy)benzene

Reaction 27: Halogenation of 1,4-bis(octyloxy)benzene with Iodine: 1,4-diiodo-2,5-bis(octyloxy)benzene

For step in multistep reaction - link to previous reaction step  
For step in multistep reaction - link to following reaction step  
Attached Files
overallscheme_28.cdx