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30th August 2013 @ 14:18

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Reaction information

*#Reaction file
ReactionScheme.cdx
 
*Reaction file type CDX 
*Procedure tert-Butyldimethylsilyl chloride (3.0 g, 20 mmol), NaI (6.0 g, 40 mmol), THF (4 mL) were dissolved in MeCN (40 mL) and stirred at 55 oC for 18 hours. After this time the solution was poured into deionised water (40 mL). Then extracted into pentanne/ether (9:1) and washed with brine. Then it was dried over MgSO4, filtered and concentrated to give the title compound.
*Yield (%) 95 
*Type of Yield Reaction Yield 
Reference(s)

M. Sodeoka, H. Yamada, M. Shibasaki, J. Am. Chem. Soc. 1990, 112, 4906. 

DavidOwenThesis2000pp36,37,94.pdf
207LABBOOK.JPG
 
Further information

Compound 207: (4-Iodobutoxy)(tert-butyl)dimethylsilane

The title compound was prepared by the method of Sodeoka et al.

For multistep reactions (or their steps):

Overall reaction? True 
For overall reaction - links to child reaction steps N/A 
For step in multistep reaction - link to previous reaction step N/A 
For step in multistep reaction - link to following reaction step N/A 
Attached Files
ReactionScheme.gif
ReactionScheme.cdx
DavidOwenThesis2000pp36,37,94.pdf
207LABBOOK.JPG