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2nd September 2013 @ 09:27

This post is compatible for submission to ChemSpider Reactions.

Reaction information

*#Reaction file	ReactionScheme.cdx
*Reaction file type	CDX
*Procedure	Cinnamyl alcohol (26.84 g, 200 mmol), triethylorthoacetate (257 mL, 227 g, 14 mol) and propanoic acid (1 mL, 1.00 g, 13.4 mmol) were heated at 130 ^oC, with the distillation of the ethanol by product. After 26 hours, excess triethylorthoacetate was removed by distillation (100 ^oC, 1 mbar) producing the desired compound with an 81 % yield.
*Yield (%)	81
*Type of Yield	Isolated Product Yield
Reference(s)	W. S. Johnson, L. Werthemann, W. R. Bartlett, T. J. Brocksom, T. T. Li, D. J. Faulkner, M. R. Petersen, J. Am. Chem. Soc. 1970, 92, 741. D. J. Faulkner, Synthesis 1971, 175. 318LABBOOK.JPG DavidOwenThesis2000pp48,112.pdf
Further information	Compound 318: Ethyl-(3-phenyl-pent-4-enoate)

For multistep reactions (or their steps):

Overall reaction?	False
For overall reaction - links to child reaction steps	N/A
For step in multistep reaction - link to previous reaction step	N/A
For step in multistep reaction - link to following reaction step	Reaction 319

Attached Files

ReactionScheme.gif

ReactionScheme.cdx

DavidOwenThesis2000pp48,112.pdf

318LABBOOK.JPG

whittam j. (jw41g11) | View Source | D. Owen | Comments (0)
Uri:https://blogs.chem.soton.ac.uk/uri/744a
Key:6d8398b3750343b744a209dc79dd4d6a
Last Updated:2nd September 2013 @ 09:37